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Creators/Authors contains: "Xiang, Zhenhua"

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  1. ; ; ; ; (, Organic Chemistry Frontiers)
    The first highly regioselective tandem indole formation/Truce–Smiles rearrangement controlled by choice of ligands for K+is presented. Use of N,N-diethylethylenediamine gives 2,3-disubstituted indoles whereas 18-crown-6 gives benzhydryl indoles. 
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  2. ; ; ; ; ; ; (, Organic Letters)
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  3. ; ; ; ; ; ; (, Advanced Synthesis & Catalysis)
    Abstract A base‐promoted net‐[3+2] cycloaddition of nitriles and 1‐arylpropynes for the synthesis of pyrroles is described. The developed method provides convenient access to various 2,5‐disubstituted or 2,4,5‐trisubstituted pyrroles in 40% to 96% yields (32 examples). Among methods for the synthesis of pyrroles, the protocol presented here stands out for its convenience and atom‐economy. 
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